Real Madrid are comfortably perched on top of the La Liga standings with 66 points while Barca are now third on 54 points with a game in hand, three points behind second-placed Sevilla.
Barcelona closed in on the La Liga title by thrashing local rivals Espanyol 5-0 on Sunday as Atletico Madrid dropped out of the race after losing 2-1 at Levante and Real Madrid beat Valencia 3-2.
Key head-to-head battles in Saturday's "Clasico" between Real Madrid and Barcelona at the Bernabeu stadium (1600 GMT)
Villarreal continued their impressive revival after a season in the second division when Jeremy Perbet and Jonathan Pereira struck in a 2-1 win at home to Espanyol in La Liga on Thursday.
Barcelona signing Robert Lewandowski is relishing a new challenge after joining the Catalan club and the 33-year-old said he was ready to play in their upcoming pre-season game against rivals Real Madrid in the United States.
Atletico Madrid's French forwards Antoine Griezmann and Kevin Gameiro fired them to a first win in three league outings as they beat Valencia 3-0 on Sunday to maintain their hold on Spain's fourth Champions League qualifying place.
The Italian said he would avoid big changes to his team this time, after he tested midfielder Luka Modric up front in place of then-injured striker Karim Benzema in the last El Clasico in March, only to get hammered 4-0 by the Catalans.
Lionel Messi scored twice as La Liga champions Barcelona saw off a persistent Valencia side, who had Eliaquim Mangala sent off in the first half, to win 4-2 on Sunday and stay on the heels of leaders Real Madrid.
David Moyes notched his maiden victory as coach of Real Sociedad as Carlos Vela scored a classy hat-trick in a morale-boosting 3-0 win at home to Elche in La Liga on Friday.
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Leaders Real Madrid pulled three points clear of second-placed Celta Vigo when they held off the valiant 10-man Galicians to secure a nervy 3-1 victory in Saturday's top-of-the-table clash in La Liga.
Arsenal sailed through the Europa League group stages, winning five of their six group matches and take on Sporting next, who overcame Denmark's FC Midtjylland in their playoff.
Real Madrid's teenage Brazilian duo Vinicius Junior and Rodrygo Goes sent them top of La Liga as both scored in a 2-0 win over Osasuna on Wednesday.
Champions Barcelona came through a gruelling La Liga test at a rainswept San Mames on Sunday, beating Athletic Bilbao 1-0 thanks to Ivan Rakitic's first-half header.
Saudi clubs have spent more than 400 million euros ($439 million) in the close season to sign players from Europe's elite teams.
Leaders Barcelona played out a second straight 0-0 draw in LaLiga after mid-table Getafe battled for a home point in a hard-fought game on Sunday.
Barcelona dropped their first points of the La Liga season as their star-studded forward line misfired in a 0-0 draw away to Malaga on Wednesday.
An insatiable Lionel Messi hit a hat-trick as Barcelona hammered Espanyol 5-0 in a local derby on Saturday to make it three wins from three and take full advantage after Liga champions Real Madrid were held to a 1-1 draw at home to Levante.
La Liga leaders Barcelona won a tight and tense 'Clasico' 1-0 at Real Madrid on Saturday, beating their great rivals at their Bernabeu home for the second time in four days and moving a staggering 12 points clear of them in the standings.
Barcelona finished three points behind Real Madrid last season but there is concern the gap between Spain's biggest two sides could be far larger this season.
Ronaldo had failed to score in his last four league games for Real and his rotten run in front of goal looked set to continue when his spot-kick was turned away by visiting goalkeeper Roberto.
Alvaro Morata again proved decisive from the bench by striking a late winner against Athletic Bilbao and firing a lacklustre Real Madrid to the top of La Liga on Sunday. The Spain international has been afforded limited opportunities in his first season back at Real following two years with Juventus, struggling to usurp first choice forwards Gareth Bale, Cristiano Ronaldo and Karim Benzema. Morata has made just four league starts, but has scored four times in all competitions.
India are struggling to find a batter for the No. 4 slot, something that has also troubled them in the previous edition in 2019 in England.
Barcelona sacked coach Ronald Koeman after Wednesday's 1-0 LaLiga defeat at Rayo Vallecano, the Catalan club said on Wednesday.
Atletico Madrid knocked Barcelona off the top of La Liga, for a day at least, as a second-half strike by Koke earned a 1-0 victory over a stubborn Malaga side on Saturday.
Dani Alves, who has denied any wrongdoing, was taken to the Brians 1 jail outside Barcelona.
English Premier League leaders Manchester City and Chelsea slugged out a magnificent 4-4 draw at Stamford Bridge.
Simeone's side leapfrogged Real Sociedad into fourth on 42 points, while Sevilla stayed third in the standings on 46 after beating Las Palmas 1-0, also on Sunday, thanks to a late strike from substitute Joaquin Correa
'Robert is an incredible player and he won everything with us. We are incredibly grateful to him.'
A first-half strike from Pedri gave Barcelona a 1-0 win over Villareal to extend their lead over Real Madrid at the top of LaLiga to 11 points
"Everything will not be complete if we don't win the Champions League now. We have done some incredible seasons."
Poland and Bayern Munich striker Robert Lewandowski hailed Barcelona coach Xavi as the main reason for his move to the La Liga club.
The Polish striker will miss games against Espanyol, Atletico Madrid and Getafe when LaLiga resumes after the World Cup.
Rodrygo struck twice and Vinicius Jr dazzled as Real Madrid beat Osasuna 2-1 on Saturday to win their 20th Copa del Rey title and first since 2014.
Given a contract until 2024, the 41-year-old made a winning start on Saturday with a victory over Espanyol that put Barcelona sixth in LaLiga on 20 points after 13 matches.
Real Madrid will join the complaint filed on Friday by Spanish prosecutors against Barcelona and two of the LaLiga club's ex-presidents over alleged payments to a company owned by a senior refereeing official to influence match results.